Behind the Brew: Exploring the Techniques of Making Decaf Coffee

Behind the Brew: Exploring the Techniques of Making Decaf Coffee


13 minute read

Listen to article
Audio is generated by DropInBlog's AI and may have slight pronunciation nuances. Learn more

Decaffeinated coffee, commonly known as decaf, is coffee that has had almost all of its caffeine content removed. The decaffeination process typically removes 97% to 99.9% of caffeine, resulting in a brew that retains the taste and aroma of coffee but has minimal stimulant effect.

Decaf coffee has been around since 1906, when a German named Ludwig Roselius patented a method for extracting caffeine that involved benzene and boiling in seawater. Today, we have much safer methods that remove caffeine and leave the coffee bean’s aroma and flavor almost intact.

How Is Decaf Coffee Made? Caffeine Extraction

The most common methods of extracting caffeine from coffee beans are the supercritical carbon dioxide process, the Swiss Water Process, and chemical solvent extraction.

Solvent-Based Methods

These methods involve soaking green coffee beans in water and then using a solvent to selectively bind to and remove caffeine. The two most common solvents are methylene chloride and ethyl acetate.

While methylene chloride can effectively remove caffeine, it is a potential carcinogen. Ethyl acetate, on the other hand, is a naturally occurring compound and is considered safer, but it may not remove as much caffeine.

Both solvents are regulated to ensure that residual amounts in decaffeinated coffee remain well below harmful levels, with industry standards and health regulations strictly limiting their presence to safeguard consumer health.

Swiss Water Process

This method uses no chemical solvents. Instead, it relies on solubility and osmosis to decaffeinate unroasted coffee beans. The beans are soaked in hot water to dissolve the caffeine, and then the water is passed through an activated charcoal filter.

The tiny pores in charcoal trap the caffeine molecules but allow the smaller flavor and oil molecules to pass through. This process is unique because it uses a completely chemical-free technology. 

The water remaining after filtration contains the water-soluble components of the green coffee beans, called Green Coffee Extract (GCE).

The initial batch of beans is discarded after the caffeine is leached out into the hot water. This caffeine-saturated but flavor-rich water (GCE) is then used to soak new batches of coffee beans.

Since the GCE is already full of flavor compounds, it extracts caffeine from fresh beans while leaving their flavor compounds largely intact.

This physical filtration method is one of the reasons why the Swiss Water Process is certified organic and can maintain coffee's organic status, recognized by bodies such as the USDA.

Coffee decaffeinated using the Swiss Water Process maintains the subtle flavor notes of specialty coffees, offering caffeine-free coffee that is both environmentally friendly and rich in taste.

FYI: At Bones Coffee, we decaffeinate our beans using the Swiss Water Process. This allows us to maintain the full-bodied flavor of our top-grade beans, and it assures us and our customers that every bit of Bones decaf coffee you buy from Bones is the safest and healthiest it can be. Enjoy freely!

Carbon Dioxide (CO2) Process

In this method, the beans are soaked in water-saturated carbon dioxide (CO2) gas under high pressure. The CO2 acts as a solvent and selectively dissolves the caffeine, leaving the flavor compounds intact. 

This method utilizes supercritical CO2—a state where the CO2 is both a liquid and a gas—which acts as an effective solvent for caffeine due to its small molecular size. 

The CO2 can penetrate the coffee beans deeply, extracting caffeine while leaving more delicate flavor compounds largely unaffected. The process is highly efficient and minimizes environmental impact because the CO2 can be recycled and reused within the system.

Carbon dioxide decaffeination is also considered one of the safest methods since it doesn't involve potentially harmful chemical solvents. However, the setup and operation costs are significant, making it more expensive than other decaffeination methods.

Important: Note that while decaf is significantly lower in caffeine content than regular coffee, it is not completely caffeine-free coffee. A typical 8-ounce (240-milliliter) cup of regular coffee contains 95–200 mg of caffeine, while the same serving of decaf contains about 2–15 mg, depending on the method of decaffeination.

How Does Decaf Coffee Taste?

two people holding full coffee cups

The taste of decaf coffee compared to regular coffee is a subject of much debate among coffee enthusiasts. While the decaffeination process aims to remove caffeine without affecting the taste, it can sometimes alter the flavor profile of the coffee beans.

The taste difference between decaf and regular coffee can be attributed to several factors:

Decaffeination Process

The method used to decaffeinate coffee can impact its taste. For instance, the Swiss Water Process, which uses water and activated charcoal, is known for preserving the coffee’s original flavors. On the other hand, methods that use solvents might result in a slightly altered taste.

Quality of Beans

The quality of the coffee beans used can also influence the taste. Some manufacturers use lower-quality beans for decaf coffee since the decaffeination process can mask inferior flavors. However, high-quality decaf coffee crafted from premium beans can taste very similar to regular coffee.

Roasting Process

The roasting process can also affect the taste of decaf coffee. Decaf beans are harder to roast evenly due to their altered structure after decaffeination, which can lead to a different flavor profile.

Brewing Method

The brewing method used can also impact the taste. For example, espresso shots of caffeine-free coffee might taste slightly different than regular espresso due to the high pressure and temperature used in brewing.

In a blind taste test, the average coffee drinker might struggle to distinguish between decaf and regular coffee, especially if the decaf coffee is of high quality and has been properly brewed. If it's a Bones flavored coffee, you definitely won’t catch the difference between regular and decaf coffee!

However, coffee connoisseurs with a refined palate might notice subtle differences in flavor, body, and acidity, which some may even prefer to regular coffee.

 

hand touching red coffee beans

What are the Health Implications of Decaf Coffee?

Decaf coffee offers a delightful solace for those who endure caffeine sensitivity and strict dietary guidelines. This specially processed brew allows everyone to indulge in the rich, comforting ritual of coffee drinking without the typical caffeine-related side effects. 

If you’re watching your caffeine intake, you’ll be glad to know that caffeine-free coffee is almost as healthy as regular coffee.

Decaf coffee, like regular coffee, is a rich source of antioxidants, which are known to have numerous health benefits. These include reducing inflammation, combating free radicals, and potentially lowering the risk of certain diseases such as heart disease and certain types of cancer.

For example, one study found that people who take 3–5 cups of coffee a day have a 15% lower risk of heart disease. Coffee also helps with depression, lowers the risk of diabetes, and helps prevent Parkinson's Disease (when caffeinated).

However, it’s important to note that the decaffeination process can sometimes result in a slight reduction in the antioxidant content compared to regular coffee. The exact difference can vary depending on the specific method of decaffeination used.

One common concern about coffee consumption is caffeine’s potential to cause dehydration due to its diuretic effect. That means it can cause the kidneys to make more urine and can contribute to water loss.

However, the total amount of fluid consumed, especially with larger coffees such as cappuccinos and Americanos, can help offset the fluid loss. Nevertheless, drinking decaf coffee can help reduce this diuretic effect.

Another health aspect to consider is the acidity of coffee. Some people find that coffee can trigger acid reflux or other digestive issues. Decaf coffee is generally less acidic than caffeinated coffee, which may make it a more comfortable choice for individuals with these conditions.

Caffeine also relaxes the sphincter muscles in the esophagus, which further contributes to reflux. The severity of this effect varies depending on factors such as the type of coffee bean and the brewing method used.

Drinking caffeine-free coffee, especially from some of the less acidic coffee roasts, helps alleviate acid reflux with almost zero caffeine intake.

Is Decaf Coffee Safe?

Yes, high-quality decaffeinated coffee is safe for consumption, especially when the methods used are the Swiss Water Process or the supercritical CO2 process.

Even when potentially harmful chemicals are used, such as methylene chloride, producers adhere to stringent safety standards set by regulatory authorities such as the U.S. Food and Drug Administration (FDA).

Ethyl acetate is considered a less harmful solvent, but it’s used with the same strict safety standards.

After decaffeination, coffee beans are washed and steamed multiple times before roasting to remove practically all the remaining solvent. The FDA mandates that any residues should not exceed 10 parts per million (ppm), which it says makes the risk to humans “essentially non-existent.”

So, is decaf coffee bad for you? The answer is no. However, as with any food or beverage, it’s important to consume decaf coffee in moderation and in a way that fits with your individual health needs and preferences.

Plus, poor quality decaf coffee obtained from questionable companies may not adhere to the strict safety standards set by regulatory authorities worldwide.

 

Important: Although caffeine-free coffee is safe for consumption, the US Environmental Protection Agency (EPA) is still proposing a ban on almost all industrial uses of methylene chloride. This is driven by the need to protect workers in factories that produce and handle the chemical, given the terrible health effects of exposure to the chemical.

How to Drink Decaf Coffee

black coffee in small cup

Decaf coffee, much like its caffeinated counterpart, is versatile and can be used in a variety of brewing methods. The decaffeination process does not significantly alter the physical properties of the coffee beans, allowing them to be ground and brewed in the same manner as regular coffee. 

Espresso

Decaf coffee can certainly be used to make espresso. The key to a good espresso is not the caffeine content, but the quality of the beans and the fineness of the grind. Some coffee connoisseurs argue that the subtle flavor differences in decaf coffee can actually add a unique twist to the espresso.

French Press

The French press method, which involves steeping coffee grounds in hot water and then pressing them to separate the liquid, works well with decaf coffee. This method allows the full flavor of the coffee to be extracted, making it a good choice for decaf beans.

Cold Brew

Decaf coffee can also be used for cold brew, a method that involves steeping coffee grounds in cold water for an extended period. This method tends to produce a smoother, less acidic coffee, which can complement the slightly milder flavor profile of decaf coffee.

Drip Coffee

Drip coffee makers can also be used with decaf coffee. This method, which involves hot water dripping through a filter containing coffee grounds, is one of the most common ways to brew coffee and works just as well with decaf.

Aeropress

The Aeropress is a relatively new brewing method that combines elements of the French press and espresso methods. It’s known for producing a clean, full-bodied cup of coffee, and it works well with decaf beans.

While decaf coffee can be used in any brewing method, it’s important to note that the flavor profile of decaf coffee can be slightly different from regular coffee due to the decaffeination process. This means that the resulting brew may taste slightly different when made with decaf coffee.

How to Choose a Good Quality Decaf Coffee?

Choosing a good quality decaf coffee can be challenging, especially with the wide variety of options available in the market. However, there are certain factors that can guide you in making an informed decision.

Check the Origin of the Coffee Beans

The quality of decaf coffee, like regular coffee, largely depends on the origin of the coffee beans. Beans from regions like Colombia, Ethiopia, and Brazil are known for their distinct flavors.

Buy Organically Decaffeinated Beans

The method used to decaffeinate the coffee beans can significantly affect the taste and quality of the coffee. The Swiss Water Process and the Carbon Dioxide Process are two methods that are known for preserving the flavor of the coffee beans. Look for these terms on the packaging.

Although high-quality coffee beans that have been organically decaffeinated are more expensive, they’re worth the extra cost to ensure a tasty and healthy batch of coffee.

Go for Light or Medium Roast

The roast level of the coffee beans can also influence the taste of the coffee. Light roasts tend to retain more of the original coffee flavor, while dark roasts have a stronger, more robust flavor.

 

Hint: Decaf coffee beans are challenging to roast even for experienced roasters. They go dark more quickly than regular beans and can be confusing. In fact, some roasters don’t decaffeinate their best beans, which affects the quality of decaf coffee.

Check Certifications

Certifications can provide assurance about the quality and ethical sourcing of the coffee. Look for certifications like Fair Trade, Organic, Rainforest Alliance, and Swiss Water.

Freshness

Coffee is best consumed fresh. Check the roast date on the packaging and try to consume the coffee within a month of this date.

Brand Reputation

Lastly, consider the reputation of the brand. Brands that are known for their quality and consistency can be a safe choice.

Summary: Don’t Be Afraid to Go Big on Decaf

Now you know how decaf coffee is made. It’s safe, it’s flavorful, and you still get most of the health benefits of caffeinated coffee.

The main bone of contention is the flavor of decaf coffee, and that’s where we come in. At Bones Coffee, we believe that decaffeinated doesn't mean diminished flavor or adventure in your cup. Embracing decaf coffee is an exciting journey into a world where you can savor bold, robust flavors without the caffeine.

We ensure that every batch is as adventurous and flavorful as our customers have come to expect. We source our beans from the best farms in Central and South America for both our caffeinated and decaf coffee blends.

That’s one reason why our decaf coffee options remain full-bodied and delicious. Another reason is that our flavored decaf coffee has the lowest calorie count to make it a perfect choice for health-conscious coffee lovers, with only 2 calories per 8 ounces.

So, don't hesitate to go big on decaf with Bones Decaf Coffee—it’s all the flavor, minimal caffeine, and endless opportunities to explore coffee in new and exciting ways.

« Back to Blog